Solar Absorption by Aerosol-Bound Nitrophenols Compared to Aqueous and Gaseous Nitrophenols.
Publication/Presentation Date
6-7-2016
Abstract
Nitrophenols are well-known absorbers of near-UV/blue radiation and are considered to be a component of solar-absorbing organic aerosol material commonly labeled brown carbon. Nitrophenols have been identified in a variety of phases in earth's atmosphere, including the gaseous, aqueous, and aerosol bound, and these different environments alter their UV-vis absorption spectra, most dramatically when deprotonated forming nitrophenolates. We quantify the impact of these different absorption profiles by calculating the solar power absorbed per molecule for several nitrophenols. For instance, aqueous 2,4-dinitrophenol absorption varies dramatically over the pH range of cloud droplets with pH = 5.5 solutions absorbing three times the solar power compared to pH = 3.5 solutions. We also measured the UV-vis spectra of 2-nitrophenol adsorbed on several aerosol substrates representative of mineral dust, inorganic salts, and organic aerosol and compare these spectra to gaseous and aqueous 2-nitrophenol. 2-Nitrophenol adsorbed on mineral and chloride aerosol substrates exhibits a red-shifted absorption band (∼450-650 nm) consistent with 2-nitrophenolate and absorbs twice the solar power per molecule compared to gaseous, aqueous, and organic aerosol-bound 2-nitrophenol. We also discuss how different nitrophenol absorption profiles alter important atmospheric photolysis rate constants [e.g., J(NO2) and J(O3)] by attenuating solar flux.
Volume
50
Issue
11
First Page
5661
Last Page
5667
ISSN
1520-5851
Published In/Presented At
Hinrichs, R. Z., Buczek, P., & Trivedi, J. J. (2016). Solar Absorption by Aerosol-Bound Nitrophenols Compared to Aqueous and Gaseous Nitrophenols. Environmental science & technology, 50(11), 5661–5667. https://doi.org/10.1021/acs.est.6b00302
PubMedID
27176618
Department(s)
Department of Emergency Medicine
Document Type
Article