Halophilic reactions of a stable silylene with chloro and bromocarbons.

Authors

Daniel F Moser
Todd Bosse
Jordan E Olson MD, Lehigh Valley Health NetworkFollow
Jessica L Moser
Ilia A Guzei
Robert West

Publication/Presentation Date

4-24-2002

Abstract

A number of disilanes have been synthesized from a stable silylene, 1 (N,N'-di-tert-butyl-1,3-diaza-2-silacyclopent-4-en-2-ylidene), and a variety of halocarbons. It is proposed that disilane formation is a result of an initial halophilic interaction between the silylene and halocarbon. Formation of disilanes from 1 and CCl4, 2a, CHCl3, 2b, CH2Cl2, 2c, benzyl chloride, 2d, and bromobenzene, 5, are described here. An X-ray crystal structure of 2b was determined.

Volume

124

Issue

16

First Page

4186

Last Page

4187

ISSN

0002-7863

Published In/Presented At

Moser, D. F., Bosse, T., Olson, J., Moser, J. L., Guzei, I. A., & West, R. (2002). Halophilic reactions of a stable silylene with chloro and bromocarbons. Journal of the American Chemical Society, 124(16), 4186–4187. https://doi.org/10.1021/ja012389b

Disciplines

Medicine and Health Sciences

PubMedID

11960428

Department(s)

Department of Pathology and Laboratory Medicine

Document Type

Article